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<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">WCD</journal-id><journal-title-group>
    <journal-title>Weather and Climate Dynamics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">WCD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Weather Clim. Dynam.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">2698-4016</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/wcd-7-843-2026</article-id><title-group><article-title>Dry and moist convective upper bounds for near-surface temperatures</article-title><alt-title>Dry-convective surface temperature upper bounds</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Nicolas</surname><given-names>Quentin</given-names></name>
          <email>quentin.nicolas@env.ethz.ch</email>
        <ext-link>https://orcid.org/0000-0002-4116-973X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Hotz</surname><given-names>Belinda</given-names></name>
          
        <ext-link>https://orcid.org/0009-0002-3725-498X</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Institute for Atmospheric and Climate Science, ETH Zürich, Zürich, Switzerland</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Quentin Nicolas (quentin.nicolas@env.ethz.ch)</corresp></author-notes><pub-date><day>27</day><month>May</month><year>2026</year></pub-date>
      
      <volume>7</volume>
      <issue>2</issue>
      <fpage>843</fpage><lpage>856</lpage>
      <history>
        <date date-type="received"><day>9</day><month>December</month><year>2025</year></date>
           <date date-type="rev-request"><day>12</day><month>December</month><year>2025</year></date>
           <date date-type="rev-recd"><day>24</day><month>April</month><year>2026</year></date>
           <date date-type="accepted"><day>28</day><month>April</month><year>2026</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2026 Quentin Nicolas</copyright-statement>
        <copyright-year>2026</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026.html">This article is available from https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026.html</self-uri><self-uri xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026.pdf">The full text article is available as a PDF file from https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e86">The current pace of climate change challenges the statistical methods used for bounding heatwave intensities, prompting the need for a physics-based upper bound to extreme surface temperatures (<inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). A recently proposed approach for deriving such a bound uses the hypothesis that convective instability limits the development of heat extremes. Here, we show that under this hypothesis, the absolute upper bound for extreme <inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>  –  obtained in the limit of zero surface humidity  –  is set by dry convection. This bound is reached when the mid-troposphere and the surface are connected by a dry adiabat. Previous work suggested that this upper bound is instead set by moist convective instability and exceeds the dry convective limit. We resolve this discrepancy by showing that moist convection only limits heatwave development in the presence of enough surface specific humidity, and that the moist convective upper bound cannot exceed the dry limit. Yet, numerous temperature profiles in observational and reanalysis records do exceed the dry convective limit. We show that these occur exclusively in regions where the boundary layer top reaches deep into the mid-troposphere, and that a near-surface superadiabatic layer (an expected feature of convective boundary layers) controls the amount by which the limit is exceeded. Our work suggests that deriving physical limits on boundary layer depth and superadiabatic layer strength, two quantities largely influenced by land surface properties, may better help constrain the intensity of future dry heatwaves. We conclude with an overview of the different upper bounds applicable in dry and moist scenarios, including the roles of processes such as entrainment and convective inhibition.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>ETH Zürich Foundation</funding-source>
<award-id>24-1 FEL-032</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung</funding-source>
<award-id>219244</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e120">Extreme heat is on the rise over vast swaths of our planet, with surface temperature records being broken at increasing rates over the past four decades <xref ref-type="bibr" rid="bib1.bibx17" id="paren.1"/>. These records come with adverse impacts on human health, ecosystems, and economy <xref ref-type="bibr" rid="bib1.bibx2 bib1.bibx31 bib1.bibx6 bib1.bibx23 bib1.bibx34" id="paren.2"><named-content content-type="pre">e.g.</named-content></xref>. In this context, it is natural to ask whether there is an upper limit to heatwave intensity. This question can be tackled using statistical methods such as extreme value theory <xref ref-type="bibr" rid="bib1.bibx8 bib1.bibx22" id="paren.3"/>. However, the current pace of climate change challenges such methods, even when they are extended to take into account a background warming rate <xref ref-type="bibr" rid="bib1.bibx28 bib1.bibx54 bib1.bibx55" id="paren.4"/>. A complementary approach, which is the one considered here, is to address the question from an atmospheric dynamics standpoint  –  in other words, to derive a physics-based upper bound for near-surface temperatures.</p>
      <p id="d2e137">In tropical dynamics, it is well known that the surface and free troposphere are strongly coupled in convective regions. This happens as moist convection removes positive buoyancy anomalies in the tropospheric column much more rapidly than these are created by large-scale processes. This process, known as convective quasi-equilibrium <xref ref-type="bibr" rid="bib1.bibx1 bib1.bibx16" id="paren.5"/>, leads vertical temperature profiles in tropical convective regions to be close to moist adiabatic above the subcloud layer. For such profiles, the boundary layer equivalent potential temperature <inline-formula><mml:math id="M3" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> equals the free-tropospheric saturation equivalent potential temperature <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>, which is a function of temperature and pressure only; i.e. free-tropospheric temperature has a one-to-one relationship with boundary layer temperature and moisture (In reality, the entrainment of dry air into convective clouds leads boundary layer <inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to be higher than this theoretical value  –  e.g. <xref ref-type="bibr" rid="bib1.bibx43" id="altparen.6"/>.). This idea has been exploited to understand the response of near-surface temperatures <xref ref-type="bibr" rid="bib1.bibx5" id="paren.7"/> and extreme moist heat <xref ref-type="bibr" rid="bib1.bibx57" id="paren.8"/> to climate change in the tropics.</p>
      <p id="d2e188"><xref ref-type="bibr" rid="bib1.bibx56" id="author.9"/> (<xref ref-type="bibr" rid="bib1.bibx56" id="year.10"/>, hereafter ZB23) explored the hypothesis that moist convection may also constrain temperature profiles over midlatitude land in summer. For a given free-tropospheric temperature profile, there is a surface temperature threshold beyond which the atmospheric column becomes unstable to moist convection; beyond this threshold, the release of instability leads to downdrafts, cooling the surface air. Making use of a simple non-entraining parcel model, along with the hypothesis that surface temperatures cannot exceed the threshold for moist convection, they derived an upper bound for near-surface temperature over midlatitude land that depends on two quantities: mid-tropospheric temperature and surface elevation. They showed that surface temperature extremes can get close to but rarely exceed this bound. The success of this theory prompted its application to policy-relevant work <xref ref-type="bibr" rid="bib1.bibx38 bib1.bibx39" id="paren.11"><named-content content-type="pre">e.g.</named-content></xref>.</p>
      <p id="d2e201">ZB23 discuss two upper bound formulations: one for parcels with a minimum amount of near-surface specific humidity <inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and a more general one obtained in the limit of zero <inline-formula><mml:math id="M7" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. One peculiar aspect of this general bound (and of the first bound, for high mid-tropospheric temperature or low <inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) is that it is higher than an upper bound derived assuming neutrality to dry convection instead of moist convection. This contradicts the elementary expectation that instability to moist convection arises before instability to dry convection. The first goal of this manuscript is to clarify the reasons for this behavior, and to show that in the absence of any constraints on surface humidity, dry convection ultimately limits surface temperatures. The second goal is to explore the behavior of temperature profiles that exceed the surface temperature limit set by dry convective neutrality. We show that these happen in arid regions where extremely deep boundary layers develop and near-surface superadiabatic layers are present. We finish by discussing the implications of these findings for the derivation of surface temperature upper bounds in dry and moist environments.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Methods</title>
      <p id="d2e245">The analyses presented in Sect. <xref ref-type="sec" rid="Ch1.S4"/> rely on two data products. The first is the ERA5 reanalysis <xref ref-type="bibr" rid="bib1.bibx24" id="paren.12"/>, from which we use June–July–August (JJA) model-level data at 0.5° horizontal resolution from 2001 to 2021. We also use ERA5 2-m temperature data, a post-processed variable obtained by interpolating between the lowest model level and the surface skin temperature following Monin–Obukhov similarity theory <xref ref-type="bibr" rid="bib1.bibx14" id="paren.13"/>. Our second data source is the Integrated Global Radiosonde Archive <xref ref-type="bibr" rid="bib1.bibx12" id="paren.14"><named-content content-type="pre">IGRA,</named-content></xref>, from which we use observational vertical profiles of temperature, geopotential height, and wind speed over the same time period. We select profiles that have valid temperature measurements from the surface to at least 400 <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>; this represents between 58 <inline-formula><mml:math id="M10" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>–72 <inline-formula><mml:math id="M11" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of days depending on the location. We use soundings from three stations, all located in the western US: Elko, NV (WMO ID: 72582), Salt Lake City, UT (WMO ID: 72572), and Riverton, WY (WMO ID: 72672).</p>
      <p id="d2e286">One important variable for our analysis is the planetary boundary layer (PBL) top pressure. We follow the ECMWF methodology <xref ref-type="bibr" rid="bib1.bibx14" id="paren.15"/> and define the boundary layer top as the first level above the surface at which the bulk Richardson number <inline-formula><mml:math id="M12" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">Ri</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> exceeds 0.25. Because moisture retrievals are frequently missing in IGRA data, we neglect virtual effects in the calculation (and in the rest of this work); <inline-formula><mml:math id="M13" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">Ri</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is defined as

              <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M14" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi mathvariant="italic">Ri</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>(</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:mi>T</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi>g</mml:mi><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>|</mml:mo><mml:mi mathvariant="bold-italic">v</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mo>|</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M15" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the heat capacity of air at constant pressure (hereafter approximated as that of dry air, 1004 <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M17" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> is temperature, <inline-formula><mml:math id="M18" display="inline"><mml:mi mathvariant="bold-italic">v</mml:mi></mml:math></inline-formula> is the horizontal wind vector, and <inline-formula><mml:math id="M19" display="inline"><mml:mi>z</mml:mi></mml:math></inline-formula> is the geopotential height. The subscript <inline-formula><mml:math id="M20" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> indicates the lowest available level (which lies near the surface) for IGRA soundings. For ERA5, we use the 2 <inline-formula><mml:math id="M21" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> level; thus, our calculation deviates from standard ECMWF practice (which uses the lowest model level) in order to be comparable to the IGRA soundings. PBL top pressures obtained from the two methods closely match in most circumstances (Fig. S1 in the Supplement), although at the hottest time of day over midlatitude land, differences of 100 <inline-formula><mml:math id="M22" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> or more do exist in extreme cases. Around 0.5 <inline-formula><mml:math id="M23" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of the IGRA soundings have missing wind speed data, which precludes estimation of the PBL top; these soundings are excluded from all analyses involving PBL top data.</p>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Dry and moist adiabatic upper bounds</title>
      <p id="d2e543">The starting point of our discussion is the following question: given a set of environmental parameters, what is the maximum achievable 2-m temperature <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at a given location on Earth? For simplicity and consistency with previous work, we take a local point of view: we seek to constrain <inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as a function of environmental quantities (e.g. free-tropospheric temperature and near-surface humidity) at the location of interest. The central hypothesis of this section is that <inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is limited by the onset of convective instability. As in ZB23, we assume that the free-tropospheric temperature profile is imposed by large-scale dynamics; <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> may increase until the point where an air parcel lifted from the surface into the free troposphere becomes positively buoyant. ZB23 chose to evaluate this buoyancy criterion at a fixed pressure level, namely 500 <inline-formula><mml:math id="M28" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>: this level is low enough to always lie below the tropopause, and high enough not to be strongly affected by surface processes (although we will see that this does not hold true in all cases). Our question then becomes: what is the highest value <inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mo>max⁡</mml:mo></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> such that any adiabatically<fn id="Ch1.Footn1"><p id="d2e615">Note that the condensation of water vapor contained in the parcel is considered an adiabatic process, as no external heat source is applied.</p></fn> lifted parcel, starting from the surface with a temperature <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mo>max⁡</mml:mo></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, is negatively or neutrally buoyant at the 500 <inline-formula><mml:math id="M31" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level?</p>
      <p id="d2e650">To answer this question, we need to know what sets the temperature of an adiabatically lifted parcel. Several quantities may be used for that purpose <xref ref-type="bibr" rid="bib1.bibx40" id="paren.16"/>. Among these, moist static energy (MSE) is the most convenient analytically, although it is not exactly conserved following adiabatic parcel motion (we come back to this point in Sect. <xref ref-type="sec" rid="Ch1.S3.SS4"/>). That is the choice ZB23 made, and that is the choice we start with. Neglecting the presence of the ice phase, which likely has little importance below 500 <inline-formula><mml:math id="M32" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> during midlatitude land heatwaves, MSE is

              <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M33" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mtext>MSE</mml:mtext><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>,</mml:mo><mml:mi>q</mml:mi><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:mi>T</mml:mi><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>q</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the hydrostatic geopotential height profile of the environment, <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> the latent heat of vaporization (taken as <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mn mathvariant="normal">2.5</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M37" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), and <inline-formula><mml:math id="M38" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> is specific humidity. Heuristically, MSE is conserved for unsaturated parcels because both specific humidity <inline-formula><mml:math id="M39" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> and dry static energy <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mtext>DSE</mml:mtext><mml:mo>=</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:mi>T</mml:mi><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi></mml:mrow></mml:math></inline-formula> are conserved following adiabatic motion (adiabatically lifted dry parcels cool with a lapse rate <inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mi>g</mml:mi><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, keeping DSE constant). For saturated parcels, a decrease <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>q</mml:mi></mml:mrow></mml:math></inline-formula> in the parcel's specific humidity increases the parcel's DSE by <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>q</mml:mi></mml:mrow></mml:math></inline-formula> through latent heating, thereby keeping its MSE constant. The MSE of a saturated parcel will be a useful quantity in the following analysis; we denote it

              <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M44" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:mi>T</mml:mi><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> is the saturation specific humidity. We now use the approximation that MSE is conserved during adiabatic parcel ascent to evaluate parcel buoyancy at 500 <inline-formula><mml:math id="M46" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Case where the parcel is saturated at 500 hPa</title>
      <p id="d2e958">Let us start with the case in which the adiabatically lifted surface parcel reaches saturation before the 500 <inline-formula><mml:math id="M47" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level. This means <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the pressure of the lifted condensation level. The parcel's initial MSE is denoted <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and is conserved during its entire ascent. Above its LCL, neglecting any effects of subsaturation, its MSE is also equal to <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the parcel's temperature at level <inline-formula><mml:math id="M54" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>. In summary,

                <disp-formula specific-use="align" content-type="numbered"><mml:math id="M55" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mtext>MSE</mml:mtext><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi>q</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>≥</mml:mo><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E4"><mml:mtd><mml:mtext>4</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mi>p</mml:mi><mml:mo>≤</mml:mo><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          The condition that the parcel be negatively or neutrally buoyant at 500 <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> is <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the environment's temperature at 500 <inline-formula><mml:math id="M59" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. The key point is: because MSE<sup>*</sup> is an increasing function of temperature, <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is equivalent to <inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>≤</mml:mo><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Thus, a negatively or neutrally buoyant parcel requires

                <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M63" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

          i.e.

                <disp-formula specific-use="align" content-type="numbered"><mml:math id="M64" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mo>max⁡</mml:mo><mml:mo>,</mml:mo><mml:mtext>moist</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E6"><mml:mtd><mml:mtext>6</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>≡</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>g</mml:mi><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup><mml:mo>-</mml:mo><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup><mml:mo>=</mml:mo><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. We will soon see that for parcels that attain the upper bound, the last term on the right-hand side can only be negative.</p>
      <p id="d2e1502">The gray line in Fig. <xref ref-type="fig" rid="F1"/> illustrates the case of a neutrally buoyant parcel, i.e. for which Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) is an equality. The reference <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is indicated by a purple star. The parcel is unsaturated at the surface, and rises dry adiabatically until it reaches saturation around 700 <inline-formula><mml:math id="M68" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. During this initial ascent phase, both the parcel's DSE and <inline-formula><mml:math id="M69" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> are conserved. Thereafter, it rises moist adiabatically, that is, along a line of constant MSE<sup>*</sup>. The parcel's <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> were chosen such that this line passes exactly through our reference <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>: that is, such that <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.</p>

      <fig id="F1"><label>Figure 1</label><caption><p id="d2e1614">Skew-<inline-formula><mml:math id="M75" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> log-<inline-formula><mml:math id="M76" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> diagram illustrating the derivation of upper bounds for surface temperature based on MSE conservation, for an example where the reference 500 <inline-formula><mml:math id="M77" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> temperature, <inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, is <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M80" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. <inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is shown as a purple star, and the moist adiabat passing through it (a line of constant MSE<sup>*</sup>) as a dashed blue line. A dry adiabatic upper bound is derived using conservation of DSE by following the dashed red line from the 500 <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level down to the surface. The ZB23 bound is the result of following the moist adiabat up into the upper troposphere, then following the constant DSE line (dotted red) that it asymptotes to back down to the surface. The profiles of two adiabatically lifted parcels that have the same <inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula> but different <inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are shown in gray and black, and their LCLs are shown as thick dots. The environmental temperature profile used to calculate <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mi>z</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the dashed blue line.</p></caption>
          <graphic xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026-f01.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Case where the parcel is unsaturated at 500 hPa</title>
      <p id="d2e1760">What happens when <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M88" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, as regularly happens over arid regions in summer? In that case, <inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>≠</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mtext>parc</mml:mtext><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula> at 500 <inline-formula><mml:math id="M90" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, so using <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msup><mml:mtext>MSE</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> to measure the parcel's temperature at 500 <inline-formula><mml:math id="M92" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> will not be of any use as we do not know its value. Instead, we can use the fact that the parcel's DSE is conserved between the surface and 500 <inline-formula><mml:math id="M93" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, because the parcel's <inline-formula><mml:math id="M94" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> does not change below the LCL: <inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msub><mml:mtext>DSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mtext>DSE</mml:mtext><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Using this relationship, <inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is now equivalent to

                <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M97" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>g</mml:mi><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d2e1948">The line of constant DSE that yields neutral buoyancy at 500 <inline-formula><mml:math id="M98" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> is illustrated in dashed red in Fig. <xref ref-type="fig" rid="F1"/>. The surface temperature value above which parcels having <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M100" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> are convectively unstable is marked as a red cross, and will hereafter be referred to as the dry adiabatic bound, or simply dry bound.</p>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Why the dry adiabatic bound cannot be exceeded for convectively neutral parcels</title>
      <p id="d2e1993">We now show that the right-hand side of Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) can never exceed the dry adiabatic bound; in other words, that <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mi>g</mml:mi><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the highest attainable surface temperature for negatively or neutrally buoyant parcels (under the approximation that MSE is conserved). For this, we consider a parcel which attains the bound in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>)  –  that is, a parcel for which <inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>(</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. The condition <inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M104" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, which is the first hypothesis in the derivation of Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>), is equivalent to <inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>&gt;</mml:mo><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>hPa</mml:mtext><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>. Thus, the term involving moisture quantities in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) is always negative, achieving the proof.</p>
      <p id="d2e2138">Equations (<xref ref-type="disp-formula" rid="Ch1.E6"/>) and (<xref ref-type="disp-formula" rid="Ch1.E7"/>) can be summarized into an upper bound valid for all values of <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> under the hypothesis that <inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is limited by convective instability:

                <disp-formula id="Ch1.E8" content-type="numbered"><label>8</label><mml:math id="M108" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>g</mml:mi><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mo movablelimits="false">min⁡</mml:mo><mml:mfenced open="[" close="]"><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup><mml:mo>-</mml:mo><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d2e2259">To derive their upper bound (their Eq. 3), ZB23 take <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to zero in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>): this is at odds with our assumption that <inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M111" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. The graphical construction leading to their upper bound is illustrated in Fig. <xref ref-type="fig" rid="F1"/>: one follows the moist adiabat passing through <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> into the upper troposphere (dashed blue line), then descends along a constant DSE line (dashed red). A parcel profile that respects the ZB23 bound but exceeds the dry upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>) is shown in black: such a parcel is neutrally buoyant in the upper troposphere, but clearly positively buoyant at the 500 <inline-formula><mml:math id="M113" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level.</p>
      <p id="d2e2322">The analysis presented above results from our own reading of ZB23, which we interpreted to rest on the assumption that a parcel lifted from the surface must be neutrally buoyant at 500 <inline-formula><mml:math id="M114" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. During the review process, we learned about a different interpretation of ZB23's upper bound (Yi Zhang and William R. Boos, personal communication, 2026). It appears when one removes the assumption that the parcel must be neutrally buoyant at the 500 <inline-formula><mml:math id="M115" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, but considers the assumption stated in ZB23 that the environment has a moist adiabatic temperature profile above the 500 <inline-formula><mml:math id="M116" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level. Under this interpretation, a surface parcel can warm until it triggers cloud formation if lifted to some level <inline-formula><mml:math id="M117" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> above the 500 <inline-formula><mml:math id="M118" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, even if it is unstable to dry convection at 500 <inline-formula><mml:math id="M119" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. Such a parcel would thus have <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mtext>parc</mml:mtext></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">a</mml:mi><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>. The additional assumption on the environment's temperature profile yields <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">a</mml:mi><mml:mo>*</mml:mo></mml:msubsup><mml:mo>=</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>. Thus, <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mtext>parc</mml:mtext></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>. In Fig. <xref ref-type="fig" rid="F1"/>, the black line illustrates the profile of a parcel that exactly attains this limit: it is positively buoyant at 500 <inline-formula><mml:math id="M123" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, but condenses around 410 <inline-formula><mml:math id="M124" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, and is neutrally buoyant thereafter. There is no lower bound on the humidity of such a parcel, so in the limit where <inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mtext>parc</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> goes to zero and cloud formation happens infinitely high in the atmosphere, then <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:msub><mml:mtext>DSE</mml:mtext><mml:mrow><mml:mi mathvariant="normal">s</mml:mi><mml:mo>,</mml:mo><mml:mtext>parc</mml:mtext></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>, which is exactly ZB23's upper bound. In this framework, the PBL top must always stay below the 500 <inline-formula><mml:math id="M127" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level; we shall see in Sect. <xref ref-type="sec" rid="Ch1.S4"/> that this condition is violated for almost all profiles exceeding the dry bound in ERA5.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <label>3.4</label><title>An aside on the non-conservation of DSE</title>
      <p id="d2e2523">Careful readers may notice in Fig. <xref ref-type="fig" rid="F1"/> that constant DSE lines slightly differ from the reference dry adiabats, which are lines of constant potential temperature <inline-formula><mml:math id="M128" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>. This is because DSE (and MSE) is not exactly conserved following adiabatic parcel displacements <xref ref-type="bibr" rid="bib1.bibx40" id="paren.17"/>. The easiest way to understand this fact is to use conservation of enthalpy: a parcel that is lifted by an amount <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi></mml:mrow></mml:math></inline-formula>, thereby undergoing a pressure change <inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>p</mml:mi></mml:mrow></mml:math></inline-formula>, experiences an enthalpy change <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>parc</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:mi mathvariant="normal">d</mml:mi><mml:mi>p</mml:mi></mml:mrow></mml:math></inline-formula>. Because the parcel's pressure equals that of the environment at all heights and the environment is hydrostatic, <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>p</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>env</mml:mtext></mml:msub><mml:mi>g</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi></mml:mrow></mml:math></inline-formula>. Hence,

                <disp-formula id="Ch1.E9" content-type="numbered"><label>9</label><mml:math id="M133" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="normal">d</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mtext>DSE</mml:mtext><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:msub><mml:mi>T</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:mi>z</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi>g</mml:mi><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>parc</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>env</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>parc</mml:mtext></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>

          A parcel that is hotter than the environment, hence less dense, will experience a decrease in DSE during adiabatic ascent; that is essentially because its enthalpy loss <inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>parc</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:mi mathvariant="normal">d</mml:mi><mml:mi>p</mml:mi></mml:mrow></mml:math></inline-formula> has a larger magnitude than <inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mtext>env</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:mi mathvariant="normal">d</mml:mi><mml:mi>p</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mi>g</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi></mml:mrow></mml:math></inline-formula>.  This explains why the dry adiabats are steeper than the constant DSE lines in Fig. <xref ref-type="fig" rid="F1"/>.</p>
      <p id="d2e2749">A more accurate version of the dry bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>) uses conservation of potential temperature and reads <inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, or equivalently

                <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M137" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:mn mathvariant="normal">500</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mtext>hPa</mml:mtext><mml:msup><mml:mo>)</mml:mo><mml:mfrac><mml:mi>R</mml:mi><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M138" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> is taken as the gas constant for dry air, 287 <inline-formula><mml:math id="M139" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. This bound is slightly less practical than Eq. (<xref ref-type="disp-formula" rid="Ch1.E7"/>) because it requires knowledge of <inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. In practice, the bound of Eq. (<xref ref-type="disp-formula" rid="Ch1.E10"/>) is on average 1.7 <inline-formula><mml:math id="M141" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> higher than that of Eq. (<xref ref-type="disp-formula" rid="Ch1.E7"/>), a sizable difference. We strive to use this bound in the rest of the paper, except for Figs. <xref ref-type="fig" rid="F2"/>a and <xref ref-type="fig" rid="F4"/>.</p>

      <fig id="F2" specific-use="star"><label>Figure 2</label><caption><p id="d2e2886"><bold>(a)</bold> Joint histogram of daily maximum <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and simultaneous <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (binned every 0.5 <inline-formula><mml:math id="M144" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>) for land grid points between 40–65<inline-formula><mml:math id="M145" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> (values from ERA5). The upper bound of ZB23 (dotted) and the DSE-based dry adiabatic upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>, dashed) are overlaid. The white star marks the position of the sounding shown in <bold>(b)</bold> and <bold>(c)</bold>. <bold>(b)</bold> Skew-<inline-formula><mml:math id="M146" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> log-<inline-formula><mml:math id="M147" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> diagram for an example profile exceeding the dry adiabatic upper bound, at 00:00 <inline-formula><mml:math id="M148" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">UTC</mml:mi></mml:mrow></mml:math></inline-formula> on 8 July 2014, at 41° N, 116° W. ERA5 temperature (red line) and dew point (green line) start from the lowest model level. Dots show the 2-m values. The profile of a non-entraining parcel rising adiabatically from the 2-m level (orange line), its LCL (orange dot), and its region of positive buoyancy (orange shading) are shown. Thin black and gray lines show a simultaneous observational sounding from Elko, NV, USA (40.86° N, 115.74° W). <bold>(c)</bold> Potential temperature profiles from ERA5 (red, dot shows the 2-m value) and observation (black). The leftmost dashed lines show the minimum <inline-formula><mml:math id="M149" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> value and corresponding pressure level. The arrow illustrates the calculation of the superadiabatic layer strength <inline-formula><mml:math id="M150" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> in ERA5.</p></caption>
          <graphic xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026-f02.png"/>

        </fig>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e3015">Characteristics of dry adiabatic bound exceedances over midlatitude land in the Northern Hemisphere (using the <inline-formula><mml:math id="M151" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>-based bound, Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>). <bold>(a)</bold> Frequency of JJA days exceeding the dry bound in ERA5 (shading; regions shaded in white never exceed the bound). Smoothed contours of 1000, 2000, and 3000 <inline-formula><mml:math id="M152" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> surface elevation are shown in light, medium, and dark brown. The thick outline emphasizes our main study region: the 0–40<inline-formula><mml:math id="M153" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi></mml:mrow></mml:math></inline-formula> N region is only included here for comparison. <bold>(b)</bold> Distribution of PBL top pressure for all JJA profiles (non-filled histogram), and instances that exceed the dry bound (filled histogram). <bold>(c)</bold> As in <bold>(b)</bold>, for a unique location: Elko, NV, USA (40.86° N, 115.74° W  –  yellow cross in <bold>a</bold>). Blue histograms show ERA5 data and red histograms use IGRA soundings. The gray shaded area indicates pressure levels below the surface. <bold>(d,e)</bold> as in <bold>(b, c)</bold>, for the superadiabatic layer strength <inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>.</p></caption>
          <graphic xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026-f03.png"/>

        </fig>

      <fig id="F4"><label>Figure 4</label><caption><p id="d2e3087">As in Fig. <xref ref-type="fig" rid="F2"/>a, for all land points between 65° S–65° N.</p></caption>
          <graphic xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026-f04.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Temperature profiles that exceed the dry adiabatic bound</title>
      <p id="d2e3107">Under the assumption that <inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is limited by the onset of convective instability, the maximum reachable <inline-formula><mml:math id="M156" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> for a given <inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is thus the dry adiabatic upper bound. Yet, ZB23 (their Fig. S7) show that many temperature profiles in reanalysis data and observations exceed this bound. All such instances are, by definition, unstable to dry convection. In this section, we investigate the characteristics of these peculiar temperature profiles.</p>
      <p id="d2e3143">Figure <xref ref-type="fig" rid="F2"/>a reproduces the analysis of ZB23, namely showing a joint histogram of <inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>g</mml:mi><mml:msub><mml:mi>z</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (i.e. near-surface DSE divided by <inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> over summer days for all Northern Hemisphere midlatitude land grid points. The upper bound of ZB23 (obtained by taking <inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula> in Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>) and the dry bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>) are calculated by assuming a fixed proportionality coefficient between <inline-formula><mml:math id="M162" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M163" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, taken as the ratio between their climatological-mean values (22.0 <inline-formula><mml:math id="M164" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), which is a good approximation on the basis of the hypsometric equation (ZB23). About 0.9 <inline-formula><mml:math id="M165" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of this phase space exceeds the DSE-based dry upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>). This number drops to 0.6 <inline-formula><mml:math id="M166" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> for the <inline-formula><mml:math id="M167" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>-based bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>).</p>
      <p id="d2e3284">Figure <xref ref-type="fig" rid="F2"/>b illustrates one case that exceeds the DSE-based dry upper bound by about 4 <inline-formula><mml:math id="M168" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> (shown as a white star in Fig. <xref ref-type="fig" rid="F2"/>a). We choose the grid point closest to Elko, NV, USA, which regularly exceeds the dry bound (see Fig. <xref ref-type="fig" rid="F3"/>) and for which daily sounding data are available. A very deep, dry adiabatic boundary layer extends to about 470 <inline-formula><mml:math id="M169" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. This is possible thanks to the extreme dryness of the near-surface air, with a relative humidity around 9 <inline-formula><mml:math id="M170" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>. Close to the surface, the profile is characterized by a strong superadiabatic layer. This feature is particularly visible in the potential temperature profile (Fig. <xref ref-type="fig" rid="F2"/>c), which decreases by over 2.5 <inline-formula><mml:math id="M171" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> in the first 10 <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> above the surface. If the presence of a superadiabatic surface layer at the bottom of a convective boundary layer is no surprise <xref ref-type="bibr" rid="bib1.bibx46" id="paren.18"><named-content content-type="pre">e.g.</named-content></xref>, the intensity of this example is notable. Importantly, it is not an artifact of the reanalysis: the sounding profile shows a similar feature, albeit slightly weaker. The total superadiabatic layer strength, defined as

              <disp-formula id="Ch1.E11" content-type="numbered"><label>11</label><mml:math id="M173" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:munder><mml:mo movablelimits="false">min⁡</mml:mo><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>&lt;</mml:mo><mml:mi>p</mml:mi><mml:mo>≤</mml:mo><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:munder><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where the subscript <inline-formula><mml:math id="M174" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> denotes the 2-m level for ERA5 data and the lowest sounding level for observational data, is 3.2 <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> in ERA5 and 2.4 <inline-formula><mml:math id="M176" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> in observations.</p>
      <p id="d2e3417">Midlatitude locations that frequently exceed the dry bound include the mountains and high plateaus of western North America and the deserts of central Asia, with rarer instances in the Anatolian and Iberian peninsulas (Fig. <xref ref-type="fig" rid="F3"/>a, focusing between 40–65<inline-formula><mml:math id="M177" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula>). Figure <xref ref-type="fig" rid="F3"/>a also includes northern tropical and subtropical regions for comparison. Apart from the Tibetan Plateau, whose surface is close enough to the 500 <inline-formula><mml:math id="M178" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level for the boundary layer to reach it on most days, the Middle Eastern and Saharan deserts appear as subtropical hotspots for the exceedance of the dry adiabatic bound.</p>
      <p id="d2e3444">The profile of Fig. <xref ref-type="fig" rid="F2"/>b suggests that two conditions are required to exceed the dry adiabatic limit: a deep boundary layer and a strong superadiabatic surface layer. Boundary layer theory indicates that the two conditions should tend to coincide, as they are both contingent on strong surface sensible heat fluxes <xref ref-type="bibr" rid="bib1.bibx46" id="paren.19"><named-content content-type="post">see also our Sect. <xref ref-type="sec" rid="Ch1.S5.SS1.SSS2"/></named-content></xref>. At the hottest time of the day over midlatitude land in summer, the boundary layer top pressure <inline-formula><mml:math id="M179" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>t,BL</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> lies anywhere between 300 <inline-formula><mml:math id="M180" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> and the surface, with most values concentrated between 700–900 <inline-formula><mml:math id="M181" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="F3"/>b). Instances exceeding the dry bound occupy the lower tail of these values, with 98.8 <inline-formula><mml:math id="M182" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of them having <inline-formula><mml:math id="M183" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>t,BL</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. Conversely, few profiles have <inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>t,BL</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M186" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> without exceeding the bound. This suggests that there is a quasi-equivalence between a PBL reaching higher than 500 <inline-formula><mml:math id="M187" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> and dry bound exceedance. This is no coincidence, given our definition of the PBL top. Indeed, for deep, dry convective PBLs, <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">Ri</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.25</mml:mn></mml:mrow></mml:math></inline-formula> is almost equivalent to <inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:mtext>DSE</mml:mtext><mml:mo>&gt;</mml:mo><mml:msub><mml:mtext>DSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>t,BL</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M191" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>  means that the 500 <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level does not meet the criterion <inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">Ri</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.25</mml:mn></mml:mrow></mml:math></inline-formula>; thus, it is almost equivalent to <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:msub><mml:mtext>DSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mtext>DSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. This also implies that the interpretation discussed in Sect. 3.3 for ZB23's bound, based on individual parcels reaching condensation in an atmosphere that is moist-adiabatic above the 500 <inline-formula><mml:math id="M195" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, does not hold for cases that exceed the dry bound.</p>
      <p id="d2e3651"><inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, which is a positive quantity by definition, has a bimodal distribution in ERA5, with one peak at 0 <inline-formula><mml:math id="M197" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> corresponding to stable boundary layers and a second around 1.5 <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="F3"/>d). When superadiabatic layers are present, they feature the largest magnitude just above the surface: when <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>, on average 73 <inline-formula><mml:math id="M200" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M201" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is contained between the 2-m level and lowest model level (around 10 <inline-formula><mml:math id="M202" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> above the surface), and 90 <inline-formula><mml:math id="M203" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> is contained within 100 <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> of the surface (not shown). Profiles that exceed the dry upper bound sample large values of <inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, with a mean of 3.8 <inline-formula><mml:math id="M206" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> and some values exceeding 8 <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>. However, a large <inline-formula><mml:math id="M208" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is not a guarantee of exceeding the bound, for example if the boundary layer is shallow.</p>
      <p id="d2e3790">Our analysis does not answer the question of what process ultimately limits surface temperature rise in such cases. ZB23's Fig. S1 indicates that little to no precipitation falls following heat extremes in regions exceeding the dry bound (compare the blue areas in our Fig. <xref ref-type="fig" rid="F3"/> to their Fig. S1), suggesting moist convection may not be the relevant process. Further study is required to settle this question; we come back to this point in Sect. <xref ref-type="sec" rid="Ch1.S5.SS1.SSS1"/>.</p>
      <p id="d2e3797">The reliability of ERA5 data in these particular superadiabatic environments is not guaranteed <xref ref-type="bibr" rid="bib1.bibx53" id="paren.20"/>. Hence, we strive to provide an observational comparison. Few radiosonde data are available in midlatitude regions that regularly exceed the dry upper bound, but three stations in the western US fit our purposes (see Sect. 2). We use 00:00 <inline-formula><mml:math id="M209" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">UTC</mml:mi></mml:mrow></mml:math></inline-formula> soundings, which are 3–4 <inline-formula><mml:math id="M210" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> after local solar noon, hence close to the hottest time of the day. These are compared to 00:00 <inline-formula><mml:math id="M211" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">UTC</mml:mi></mml:mrow></mml:math></inline-formula> ERA5 data at the closest grid point (days where sounding data are unavailable are also excluded in ERA5). ERA5 captures the distribution of PBL tops in Elko (Fig. <xref ref-type="fig" rid="F3"/>c) relatively well, but overestimates the highest PBLs at that location and time of day (and underestimates the occasional presence of shallow PBLs). The strength of superadiabatic layers is around twice as high in ERA5 as in observations. These two biases lead ERA5 to exceed the dry adiabatic bound twice too frequently at that location. ERA5 better captures the frequency of days exceeding the dry bound in Salt Lake City and Riverton (Fig. S2 in the Supplement). This happens as it better estimates PBL heights there. <inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is strongly overestimated in Salt Lake City, but is very well captured in Riverton. Overall, this suggests that exceedance of the dry adiabatic bound is not an artifact of the reanalysis, which captures its frequency relatively well. However, the reanalysis seems to suffer from biases in near-surface temperature profiles.</p>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Discussion</title>
      <p id="d2e3852">Our findings have implications for the derivation and application of <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> upper bounds in both dry and moist regimes. The goal of this section is to summarize these implications. Section <xref ref-type="sec" rid="Ch1.S5.SS1"/> discusses avenues for obtaining a universal upper bound for extreme surface temperature by constraining both the maximum depth of the PBL and the strength of superadiabatic layers. Section <xref ref-type="sec" rid="Ch1.S5.SS2"/> discusses the range of validity of the “moist convectively limited” upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>), its relevance to understanding trends in extreme surface temperatures, and how the effects of cloud entrainment and convective inhibition can lead this bound to be breached.</p>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Surface temperature upper bound over dry surfaces</title>
      <p id="d2e3879">We have shown in Sect. <xref ref-type="sec" rid="Ch1.S3"/> that under the assumption of convective neutrality, the absolute upper limit for <inline-formula><mml:math id="M214" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the dry adiabatic bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>). There are two issues with this bound. First, for temperature profiles at or above the bound, the 500 <inline-formula><mml:math id="M215" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level lies within the boundary layer (Fig. <xref ref-type="fig" rid="F3"/>b): in such cases, <inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> becomes strongly coupled to surface processes, and is thus less relevant as a control parameter. Second, the assumption of convective neutrality does not always hold, leading it to be exceeded by up to 8 <inline-formula><mml:math id="M217" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> in ERA5 and 5 <inline-formula><mml:math id="M218" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> in the observations we considered (Fig. <xref ref-type="fig" rid="F3"/>e). We discuss how to remedy these two issues in the following subsections.</p>
<sec id="Ch1.S5.SS1.SSS1">
  <label>5.1.1</label><title>Considerations on the free-tropospheric reference level</title>
      <p id="d2e3944">The view embraced by ZB23 is that of a “top-down” control on heatwaves: large-scale atmospheric dynamics set <inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, which in turn sets an absolute limit on the temperatures of lower levels. This contrasts with a more classical “bottom-up” view, in which the intensity of heatwaves is largely driven by surface processes, particularly sensible heat fluxes <xref ref-type="bibr" rid="bib1.bibx47 bib1.bibx36" id="paren.21"><named-content content-type="pre">e.g.</named-content></xref>. The strength of the “top-down” approach is that it trades complex land surface processes for a perhaps simpler quantity driven by large-scale dynamics. However, as discussed above, this “top-down” view breaks down for some of the strongest heat extremes, where <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> becomes coupled to the land surface.</p>
      <p id="d2e3974">Given this, one may decide to choose a higher reference level. For example, the 300 <inline-formula><mml:math id="M221" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level always remains above the boundary layer over midlatitude land in ERA5 (Fig. <xref ref-type="fig" rid="F3"/>b), so a 300 <inline-formula><mml:math id="M222" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>-based dry bound is never exceeded (Fig. S3a in the Supplement). However, the boundary layer only approaches the 300 <inline-formula><mml:math id="M223" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level over high surfaces, hence a 300 <inline-formula><mml:math id="M224" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> – based bound is unrealistically large in most regions. Conversely, there is no obvious reason to discard the possibility of a future event reaching a deeper PBL than 300 <inline-formula><mml:math id="M225" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e4020">Rather than fixing an <italic>a priori</italic> reference level, a more fruitful approach may be to predict the maximum PBL depth reachable in a given region, and to use that level to define a region-specific dry adiabatic upper bound. Process-based studies of PBL growth over land have traditionally embraced the “bottom-up” approach, in which PBL growth is modeled over the course of one day from prescribed early morning initial conditions. The approach usually consists in coupling a land surface model to a bulk model of the convective boundary layer, which grows by entrainment of free-tropospheric air <xref ref-type="bibr" rid="bib1.bibx35 bib1.bibx10 bib1.bibx50 bib1.bibx20 bib1.bibx36 bib1.bibx48" id="paren.22"><named-content content-type="pre">e.g.</named-content></xref>, or to a more complex single column model <xref ref-type="bibr" rid="bib1.bibx45" id="paren.23"><named-content content-type="pre">e.g.</named-content></xref>. In these frameworks, PBL growth is largely determined by free-tropospheric stability and the surface sensible heat flux. The latter is in turn governed by the partitioning of net surface radiation into sensible and evaporative components, the latter decreasing over soils with high evaporative resistance, particularly dry soils <xref ref-type="bibr" rid="bib1.bibx42" id="paren.24"><named-content content-type="pre">see the soil-moisture-limited regime described in, e.g.</named-content></xref>. Another takeaway is that the growth of very deep PBLs usually occurs over several days, with the energy accumulated from strong surface sensible heat fluxes being stored at night in a deep residual layer <xref ref-type="bibr" rid="bib1.bibx18 bib1.bibx41 bib1.bibx3 bib1.bibx36 bib1.bibx7" id="paren.25"/>.</p>
      <p id="d2e4044">Such initial-value integrations, however, may offer little clue to the potential existence and value of a <italic>highest reachable</italic> PBL depth. Indeed, they only focus on the processes that grow the PBL, not those that may arrest its growth. As put forward by ZB23, one such process could be cloud formation, and it was explored by many land-atmosphere coupling studies, both on the timescale of a single day <xref ref-type="bibr" rid="bib1.bibx58 bib1.bibx15 bib1.bibx51 bib1.bibx26 bib1.bibx27 bib1.bibx49 bib1.bibx52 bib1.bibx21 bib1.bibx33" id="paren.26"/> and on longer timescales <xref ref-type="bibr" rid="bib1.bibx44 bib1.bibx29" id="paren.27"/>. However, it remains uncertain whether cloud formation is relevant to limiting PBL growth in the extremely dry cases considered here. We propose two alternative processes. Radiative cooling acts to limit free-tropospheric temperature increase on <inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:mi mathvariant="script">O</mml:mi><mml:mo>(</mml:mo><mml:mn mathvariant="normal">10</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">d</mml:mi></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, and one may envision the approach of an equilibrium where radiative cooling, dry convective heating and subsidence warming are in balance throughout the atmospheric column, determining a particular equilibrium PBL height. Alternatively, such an equilibrium might never be reached on the synoptic timescale; the limiting factor for PBL growth would then simply be the lifetime of the weather system supporting it. The relevance of these processes to very deep PBLs in dry environments deserves further study.</p>
      <p id="d2e4075">It is worth noting that <xref ref-type="bibr" rid="bib1.bibx19" id="text.28"/> attempted to estimate upper limits for surface skin temperatures by considering solely the surface energy budget. However, the relevance of that work to constrain near-surface temperature <inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is compromised by the fact that <inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> was an input of the model. Resolving this issue would require coupling Garratt's model to an atmospheric column, which brings us back to the above-mentioned studies of land-PBL coupling.</p>
</sec>
<sec id="Ch1.S5.SS1.SSS2">
  <label>5.1.2</label><title>Controls on the superadiabatic layer strength</title>
      <p id="d2e4111">Our study highlights that deviations from convective neutrality due to surface-layer gradients (measured by the superadiabatic layer strength, <inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>) may modulate <inline-formula><mml:math id="M230" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> by several K for a given mixed-layer temperature (Fig. <xref ref-type="fig" rid="F3"/>d and e). Hence, one who wishes to obtain a universal upper bound for extreme temperatures likely needs to build an understanding of <inline-formula><mml:math id="M231" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. We emphasize that superadiabatic layers are no new discovery, and are in particular a classical component of any land-atmosphere coupling model (studies using bulk PBL models usually represent it as a discontinuity between surface and mixed-layer <inline-formula><mml:math id="M232" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>). Nevertheless, we provide a short review of its physical controls below for the interested reader.</p>
      <p id="d2e4160">Simple models of convective boundary layers predict <inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> to increase with the surface sensible heat flux <xref ref-type="bibr" rid="bib1.bibx16" id="paren.29"><named-content content-type="pre">e.g.</named-content></xref>. The argument goes like the following: In the surface layer (roughly the lowest 10 <inline-formula><mml:math id="M234" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula> of the boundary layer), the upward sensible heat flux <inline-formula><mml:math id="M235" display="inline"><mml:mover accent="true"><mml:mrow><mml:msup><mml:mi>w</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:msup><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> is approximately constant with height. Flux-gradient theory expresses this flux as

                  <disp-formula id="Ch1.E12" content-type="numbered"><label>12</label><mml:math id="M236" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mover accent="true"><mml:mrow><mml:msup><mml:mi>w</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:msup><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi>K</mml:mi><mml:mi>h</mml:mi></mml:msub><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi mathvariant="italic">θ</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>z</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M237" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi>h</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is a turbulent diffusion coefficient. At heights larger than the surface roughness length (<inline-formula><mml:math id="M238" display="inline"><mml:mi mathvariant="script">O</mml:mi></mml:math></inline-formula>(1–10 <inline-formula><mml:math id="M239" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) for the arid surfaces over which most dry convective cases take place), <inline-formula><mml:math id="M240" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi>h</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is captured by Monin–Obukhov similarity theory:

                  <disp-formula id="Ch1.E13" content-type="numbered"><label>13</label><mml:math id="M241" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>K</mml:mi><mml:mi>h</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">κ</mml:mi><mml:mi>z</mml:mi><mml:msup><mml:mi>u</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:msqrt><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn><mml:mi>z</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="script">L</mml:mi></mml:mrow></mml:msqrt><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M242" display="inline"><mml:mi mathvariant="italic">κ</mml:mi></mml:math></inline-formula> is the Von Karman constant, <inline-formula><mml:math id="M243" display="inline"><mml:mrow><mml:msup><mml:mi>u</mml:mi><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> the turbulent velocity and <inline-formula><mml:math id="M244" display="inline"><mml:mi mathvariant="script">L</mml:mi></mml:math></inline-formula> the Obukhov length. The specific functional form of the last term is valid for convective boundary layers and known as the Businger–Dyer profile <xref ref-type="bibr" rid="bib1.bibx4 bib1.bibx13" id="paren.30"/>. <inline-formula><mml:math id="M245" display="inline"><mml:mi mathvariant="script">L</mml:mi></mml:math></inline-formula> is itself proportional to <inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mover accent="true"><mml:mrow><mml:msup><mml:mi>w</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:msup><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:mrow></mml:math></inline-formula>. Equations (<xref ref-type="disp-formula" rid="Ch1.E12"/>)–(<xref ref-type="disp-formula" rid="Ch1.E13"/>) may be integrated from the 2-m level to the mixed layer, yielding a monotonic relationship between <inline-formula><mml:math id="M247" display="inline"><mml:mover accent="true"><mml:mrow><mml:msup><mml:mi>w</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:msup><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> and <inline-formula><mml:math id="M248" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e4430">To first order, <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is thus controlled by the surface sensible heat flux, a relationship that holds relatively well for midlatitude land summer conditions (Fig. S4 in the Supplement; part of the scatter is likely attributable to variations in mechanical turbulence, i.e. <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:msup><mml:mi>u</mml:mi><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>). Controls on surface sensible heat fluxes during heatwaves are relatively well understood thanks to land-atmosphere coupling studies (see Sect. <xref ref-type="sec" rid="Ch1.S5.SS1.SSS1"/>), suggesting a promising way forward to constrain <inline-formula><mml:math id="M251" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e4472">In light of these considerations, it may appear surprising that the ZB23 upper bound fits the upper edge of the <inline-formula><mml:math id="M252" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M253" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> relationship so well in Fig. <xref ref-type="fig" rid="F2"/>a. Because the difference between their upper bound and the dry adiabatic upper bound is given by <inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, this may suggest that the maximum superadiabatic layer strength is given by <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:msup><mml:mi>q</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. We do not see any obvious physical explanation for such a relationship; it may simply stem from the fact that higher <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> correlates with more equatorward locations and stronger anticyclonic conditions, both allowing for higher sensible heat fluxes and ultimately higher <inline-formula><mml:math id="M257" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. It is important to note that hot extremes never reach the ZB23 bound at higher <inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; it is by no means evident that one can use the bound to extrapolate the behavior of <inline-formula><mml:math id="M259" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> extremes over dry surfaces to climate change. Figure <xref ref-type="fig" rid="F4"/> explores a higher range of <inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> variations by considering the <inline-formula><mml:math id="M261" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> relationship over all non-polar land regions, and shows a clear departure from the ZB23 upper bound at high values of <inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>: <inline-formula><mml:math id="M264" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> (measured by the upward deviation from the dashed line) clearly seems to plateau rather than follow the dotted line. However, Fig. <xref ref-type="fig" rid="F4"/> must be interpreted with caution as the top-right range of the histogram is occupied by high-elevation regions (Fig. S5 in the Supplement), mostly over the Tibetan Plateau.</p>
</sec>
</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Upper bound over moist surfaces</title>
<sec id="Ch1.S5.SS2.SSS1">
  <label>5.2.1</label><title>Range of validity of the bound</title>
      <p id="d2e4688">Over moist surfaces, the surface temperature threshold for convective instability is lowered by an amount <inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup><mml:mo>)</mml:mo><mml:mo>/</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi>p</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> compared to dry surfaces (Eqs. <xref ref-type="disp-formula" rid="Ch1.E6"/> and <xref ref-type="disp-formula" rid="Ch1.E8"/>). This “moist convective” upper bound is only valid when the LCL of near-surface air is below the 500 <inline-formula><mml:math id="M266" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, i.e. when <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≥</mml:mo><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>. This raises an important caveat: even over climatologically “moist” regions, such as western Europe, extreme surface dryness may push the moist bound outside of its zone of validity. For example, the “realistic” upper bounds that <xref ref-type="bibr" rid="bib1.bibx38" id="text.31"/> derived for European cities (obtained in the limit of record-low surface specific humidity) all have error bars exceeding 54 <inline-formula><mml:math id="M268" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>, whereas the <inline-formula><mml:math id="M269" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>-based dry upper bound is 50.5 <inline-formula><mml:math id="M270" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> for <inline-formula><mml:math id="M271" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">264</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M272" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> (their highest <inline-formula><mml:math id="M273" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> value, as implied by the absolute upper bounds they report) assuming <inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1020</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M275" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> (which is on the upper end of values relevant for summer heatwave conditions). This does not discard the possibility of 50 <inline-formula><mml:math id="M276" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> being reached in these cities in the current climate, but conditions it on the existence of much deeper boundary layers than ever observed (the highest PBL top of the 2001–2021 period in ERA5 stands at 580 <inline-formula><mml:math id="M277" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> in the cities considered in that study) and possibly strong superadiabaticity.</p>
</sec>
<sec id="Ch1.S5.SS2.SSS2">
  <label>5.2.2</label><title>Explanation of the observed trends in extreme surface temperature</title>
      <p id="d2e4874">ZB23 showed that when taking an average over all midlatitude land TXx events (the warmest time of the year at any given location), the moist upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>) is exactly attained. They subsequently used this result to explain the observed rate of increase of the globally averaged temperature anomaly during TXx events (which is twice the rate of global mean warming). Our results do not call this argument into question, as the moist upper bound remains valid over most midlatitude land, provided conditions are not anomalously dry. Our results do, however, question the applicability of this argument at a local scale. For example, it is far from clear that TXx events over arid regions (which are limited by dry convection) should increase as strongly as the midlatitude-land-averaged TXx (which is limited by moist convection).</p>
</sec>
<sec id="Ch1.S5.SS2.SSS3">
  <label>5.2.3</label><title>Deviations from convective neutrality in moist cases: effects of entrainment and convective inhibition</title>
      <p id="d2e4887">Although the average midlatitude land TXx event respects the moist upper bound (ZB23), past heatwaves have locally exceeded it by more than 5 <inline-formula><mml:math id="M278" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx25" id="paren.32"/>. We list here three possible reasons for such behavior, in cases where the surface is moist enough for Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) to be relevant.</p>

      <fig id="F5" specific-use="star"><label>Figure 5</label><caption><p id="d2e4905">Idealized Skew-<inline-formula><mml:math id="M279" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> log-<inline-formula><mml:math id="M280" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> diagrams that illustrate lower-tropospheric temperature profiles associated with different surface temperature upper bounds (shown by black crosses). In all panels, purple features denote environmental conditions, while black lines are parcel profiles achieving (or exceeding) an upper bound. Reference dry adiabats, moist adiabats, and mixing lines are respectively shown in red, blue, and green. Cases shown are <bold>(a)</bold> the dry adiabatic upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>), <bold>(b)</bold> the moist upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>), <bold>(c)</bold> an entrainment-adjusted moist upper bound, and <bold>(d)</bold> a CIN-adjusted moist upper bound. See text for descriptions.</p></caption>
            <graphic xlink:href="https://wcd.copernicus.org/articles/7/843/2026/wcd-7-843-2026-f05.png"/>

          </fig>

      <p id="d2e4945">The first reason concerns the difference between boundary-layer averaged properties and near-surface properties. To derive Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>), we use the properties of a parcel that is lifted from the 2-m level to the mid-troposphere. Thermals rising from the boundary layer, however, will sample average properties of the boundary layer. The average boundary layer MSE is lower than the 2-m MSE owing to vertical moisture gradients and near-surface superadiabaticity (which, although weaker over moist surfaces, remains common in ERA5 during the hottest part of the day  –  see Fig. <xref ref-type="fig" rid="F3"/>d). Thus, <inline-formula><mml:math id="M281" display="inline"><mml:mrow><mml:msub><mml:mtext>MSE</mml:mtext><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> can exceed <inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:msubsup><mml:mtext>MSE</mml:mtext><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>, which is equivalent to the moist bound being exceeded, without moist convection developing  –  simply because convective elements rising from the boundary layer are unlikely to be as warm (in the <inline-formula><mml:math id="M283" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> or DSE sense) and moist as the near-surface air.</p>
      <p id="d2e4984">The second reason is the entrainment of dry free-tropospheric air into convective clouds. The moist upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>) is derived based on the properties of a parcel that does not mix with its environment as it rises. In practice, the entrainment of environmental air into a convective cloud reduces its buoyancy. Figure <xref ref-type="fig" rid="F5"/>c illustrates this effect: an entraining parcel cools more rapidly in its saturated ascent phase, thus requires a higher surface temperature than an undiluted parcel to reach the same 500 <inline-formula><mml:math id="M284" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> temperature. The effect is more pronounced when the environmental air is dry. Based on an idealized entraining plume model, <xref ref-type="bibr" rid="bib1.bibx11" id="text.33"/> proposed to scale the reduction in buoyancy due to entrainment as a function of the subsaturation of the environment at the 850 <inline-formula><mml:math id="M285" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level. While their study targeted tropical regions, this process is likely also relevant in midlatitudes. However, one must keep in mind that the entrainment of dry air into rising clouds is only possible above the LCL: thus, Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) may be corrected by a term depending on the subsaturation between the LCL and 500 <inline-formula><mml:math id="M286" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>, as well as the depth of the entraining layer. In particular, the entrainment of dry air into convective clouds at the 850 <inline-formula><mml:math id="M287" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level is unlikely to be relevant for heat extremes in the dry western US <xref ref-type="bibr" rid="bib1.bibx39" id="paren.34"/>, as the LCL often lies far above this level; including its effect may lead to unrealistically high upper bounds. Evidently, this process is irrelevant in cases where <inline-formula><mml:math id="M288" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mtext>LCL</mml:mtext></mml:msub><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M289" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e5055">The third reason that may explain instances exceeding Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) is the presence of convective inhibition (CIN): a warm layer between the surface and the 500 <inline-formula><mml:math id="M290" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level may prevent the release of instability, allowing the surface to warm past Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) and accumulate substantial convective available potential energy (CAPE). Figure <xref ref-type="fig" rid="F5"/>d provides a graphical illustration. However, this effect should remain small except in instances of large CAPE (ZB23), which we expect to be marginally relevant for heatwaves, but are likely relevant for moist heatwaves <xref ref-type="bibr" rid="bib1.bibx32" id="paren.35"/>. Furthermore, the parcel-based view of convective inhibition should be interpreted with caution, as wide updrafts can overcome CIN layers due to non-local buoyancy effects <xref ref-type="bibr" rid="bib1.bibx30" id="paren.36"/>. Note that convective inhibition is also irrelevant to dry convective cases, as CIN layers have no equivalent for dry convection: they would require superadiabaticity away from the surface, which can only persist for short time spans.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <label>6</label><title>Conclusions</title>
      <p id="d2e5089">This study discusses physics-based upper bounds for extreme surface temperature. We talk about “bounds”, rather than a single bound, because different starting hypotheses and different surface humidity conditions lead to different upper bounds. We use the approach of ZB23, which attempts to constrain surface temperature <inline-formula><mml:math id="M291" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as a function of mid-tropospheric temperature and surface height (and potentially specific humidity) by assuming that convective instability limits <inline-formula><mml:math id="M292" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e5114">Our central point is that the highest temperature reachable by a near-surface parcel that remains convectively stable at 500 <inline-formula><mml:math id="M293" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> is the dry adiabatic bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>). This bound is simply obtained by following a dry adiabat from <inline-formula><mml:math id="M294" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> down to the surface, as illustrated in Fig. <xref ref-type="fig" rid="F5"/>a in dashed black. A less accurate version of that bound (but which dispenses from the knowledge of <inline-formula><mml:math id="M295" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), based on the conservation of DSE, is Eq. (<xref ref-type="disp-formula" rid="Ch1.E7"/>). The upper bound derived by ZB23 (their Eq. 3) exceeds the dry adiabatic bound because it allows for parcels with significant buoyancy at 500 <inline-formula><mml:math id="M296" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>. However, this bound relies on the hypothesis that the 500 <inline-formula><mml:math id="M297" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level is within the free troposphere (equivalently, that the PBL top is below the 500 <inline-formula><mml:math id="M298" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level), which does not hold in ERA5 data for profiles that exceed the dry bound.</p>
      <p id="d2e5178">Observations and reanalysis data show that the dry bound can be breached by more than 5 <inline-formula><mml:math id="M299" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>. Temperature profiles that exceed this bound are, by definition, unstable to dry convection. They all feature a superadiabatic layer (a layer in which potential temperature decreases with height), which is always located close to the surface, and is an expected feature of dry convective boundary layers. Figure <xref ref-type="fig" rid="F5"/>a illustrates a typical such profile in solid black; the difference between the near-surface <inline-formula><mml:math id="M300" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and the mixed-layer <inline-formula><mml:math id="M301" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> is termed superadiabatic layer strength (<inline-formula><mml:math id="M302" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mtext>SA</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>). Instances that exceed the dry adiabatic bound occur exclusively in arid regions, and primarily over high altitude surfaces: Indeed, a quasi-necessary condition for exceeding the dry adiabatic bound is that the PBL top reaches above the 500 <inline-formula><mml:math id="M303" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, which happens more readily over elevated surfaces. In such conditions, <inline-formula><mml:math id="M304" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> may not reliably be considered an external control on surface temperature  –  understanding the processes that can limit PBL growth over dry surfaces may be a more fruitful approach to bounding heatwave intensities in these cases.</p>
      <p id="d2e5238">If near-surface specific humidity (perhaps more precisely, boundary layer averaged specific humidity) is large enough for clouds to form below the 500 <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level  –  i.e. larger than <inline-formula><mml:math id="M306" display="inline"><mml:mrow><mml:msubsup><mml:mi>q</mml:mi><mml:mn mathvariant="normal">500</mml:mn><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>  –  the hypothesis that convective instability limits <inline-formula><mml:math id="M307" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> leads to a tighter upper bound (Eq. <xref ref-type="disp-formula" rid="Ch1.E6"/>). Figure <xref ref-type="fig" rid="F5"/>b illustrates graphically how this moist convective upper bound is obtained: one follows a moist adiabat from <inline-formula><mml:math id="M308" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> down to the LCL, then a dry adiabat down to the surface. Several effects may lead <inline-formula><mml:math id="M309" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to exceed this bound without convection occurring, among which the entrainment of dry air into rising clouds (which increases the lapse rate in the saturated phase of the parcel's ascent, see Fig. <xref ref-type="fig" rid="F5"/>c), and the presence of a CIN layer (which may prevent parcels from convecting up to the 500 <inline-formula><mml:math id="M310" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> level, see Fig. <xref ref-type="fig" rid="F5"/>d).</p>
      <p id="d2e5313">The current conceptual understanding of heatwaves can be grossly divided into two schools of thought. One of these adopts a “bottom-up” approach in which land surface properties play a key role in setting heatwave intensity. The other emphasizes a “top-down” control, whereby free tropospheric temperature caps heatwave intensity by controlling the threshold for convective instability. We suggest that a purely “top-down” approach may not be justified over dry land surfaces, where the influence of the surface may reach deep into the mid-troposphere, and where the surface superadiabatic layer may modulate the strength of the hottest extremes by several degrees. This reaffirms the importance of land surface processes in setting the strongest heatwaves. We argue that further understanding of the physical limits on PBL depth and surface superadiabaticity is required, not only to constrain the intensity of heat extremes but also their regional trends. Reliable projections of future record-breaking heatwaves would greatly benefit from further research on these topics.</p>
</sec>

      
      </body>
    <back><notes notes-type="codedataavailability"><title>Code and data availability</title>

      <p id="d2e5320">The ERA5 datasets are available from the Copernicus Climate Change Service (C3S) Climate Data Store <xref ref-type="bibr" rid="bib1.bibx9" id="paren.37"><named-content content-type="post"><ext-link xlink:href="https://doi.org/10.24381/cds.143582cf" ext-link-type="DOI">10.24381/cds.143582cf</ext-link></named-content></xref>. The code used in producing the figures and some processed ERA5 and IGRA data are available at Zenodo <xref ref-type="bibr" rid="bib1.bibx37" id="paren.38"/>.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d2e5332">The supplement related to this article is available online at <inline-supplementary-material xlink:href="https://doi.org/10.5194/wcd-7-843-2026-supplement" xlink:title="pdf">https://doi.org/10.5194/wcd-7-843-2026-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e5341">QN conceptualized the study and wrote the original draft. Both authors contributed to the analysis and to the plots, and both authors reviewed and edited the paper.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e5347">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e5353">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. The authors bear the ultimate responsibility for providing appropriate place names. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><ack><title>Acknowledgements</title><p id="d2e5359">The authors would like to thank William Boos, Robin Noyelle, Lukas Papritz, and Yi Zhang for helpful discussions and feedback, as well as Heini Wernli for his great insights and support. They are also grateful to Michael Byrne and one anonymous reviewer for their constructive comments which helped improve the discussion.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e5364">This research has been supported by the ETH Zürich Foundation (grant no. 24-1 FEL-032) and the Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (grant no. 219244).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e5371">This paper was edited by David Battisti and reviewed by Michael Byrne and one anonymous referee.</p>
  </notes><ref-list>
    <title>References</title>

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